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(S)-(-)-t-Butylsulfinamide

Synonyms: (S)-(-)-2-Methyl-propane-2-sulfinic acid amide
Cat. No.: CR00002 CAS No.: 343338-28-3
MDL.: MFCD05861480 Formula: (CH3)3CS(O)NH2
F.W.121.20 Purity:
Storage:
 
Size/Unit Price Qty Availability Price Total
1g $65.00 Enter qty and click checkbox $65.00
5g $205.00 Enter qty and click checkbox $205.00
Catalog Number: CR00002   CAS No.: 343338-28-3
MDL: MFCD05861480 Formula: (CH3)3CS(O)NH2
F.W.: 121.20 Purity:
Package: Unit: g
Appearance: M.P.: 97-101 °C(lit.)
B.P.: Density:
Optical Rotation: [a]20/D -4.5°, c = 1 in chloroform Refractive Index:
Solubility: Stability:
Storage: Category: Chiral Reagents
Reference: Can be readily transformed into P,N-sulfinyl imine ligands through condensation with aldehydes and ketones, which can undergo iridium-catalyzed asymmetric hydrogenation of olefins.1 Chiral auxiliary used in an asymmetric preparation of trifluoroethylamines by conversion of trifluoroacetaldehyde to a chiral imine followed by treatment with an aryl lithium and acidic methanolysis. Useful reagent for synthesizing chiral amines.